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p-Acetylbenzylidene triphenylarsonium ylide initiated radical polymerization of methyl acrylate

✍ Scribed by S. P. Tiwari; C. L. Gehlot; A. K. Srivastava

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
244 KB
Volume
110
Category
Article
ISSN
0021-8995

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πŸ“œ SIMILAR VOLUMES

Kinetics and mechanism of the radical co
Kinetics and mechanism of the radical copolymerization of 4-vinyl pyridine with methyl acrylate initiated by p-acetylbenzylidene triphenylarsonium ylide
✍ S. P. Tiwari; C. L. Gehlot πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 137 KB πŸ‘ 2 views

## Abstract The free‐radical copolymerization of 4‐vinyl pyridine (4‐VP) with methyl acrylate (MA) initiated by __p__‐acetylbenzylidene triphenylarsonium ylide at 60 Β± 0.1Β°C with dioxane as an inert solvent yielded random copolymers. The kinetic equation was __R__~__p__~ ∝ [Ylide]^0.83^[4‐VP]^0.33^

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Solution terpolymerization of styrene (Sty), acrylonitrile (AN) and copper acrylate (CuA) has been carried out in dimethylformamide at 90Β°C for 4 h using p-acetyl benzylidene triphenylarsonium ylide as radical initiator. 'H nuclear magnetic resonance (NMR), IR and elemental analysis have been used t