Ozonolysis of 3,4-dehydroproline
✍ Scribed by V. Nair; K. H. Kim; R. H. Walsh
- Book ID
- 112124017
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1977
- Tongue
- English
- Weight
- 179 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0022-152X
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## Abstract The conformational study of __N__‐acetyl‐__N__′‐methylamide of L‐3,4‐dehydroproline (Ac‐Dhp‐NHMe, the Dhp dipeptide) is carried out using hybrid density functional methods with the self‐consistent reaction field method in the gas phase and in solution (chloroform and water). The incorpo
As a model for the tritium labelling of peptides the catalytic deuteration of N-acetyl-OL-3,4-dehydroproline amide was investigated by means of mass spectrometric measurements. The unwanted incorporation of hydrogen instead of deuterium, found especially in the presence of water, was compensated par