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Ozone decomposition in water studied by pulse radiolysis. 1. Perhydroxyl (HO2)/hyperoxide (O2-) and HO3/O3- as intermediates

โœ Scribed by Buehler, Rolf E.; Staehelin, J.; Hoigne, J.

Book ID
111859918
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
623 KB
Volume
88
Category
Article
ISSN
0022-3654

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Ozone decomposition in water studied by
Ozone decomposition in water studied by pulse radiolysis. 2. Hydroxyl and hydrogen tetroxide (HO4) as chain intermediates
โœ Staehelin, J.; Buehler, R. E.; Hoigne, J. ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 679 KB

Ozone decomposition in pure water involves a chain mechanism, initiated by the reaction OH-+ O3 and propagated by 02and OH. In the present studies this chain is initiated by pulse radiolysis of aqueous solutions of ozone. The chain propagation steps were studied in two parts: (I) 0, -0, -H 0 3 -OH a