Oxygenation of Alkane C—H Bonds with Methyl(trifluoromethyl)dioxirane: Effect of the Substituents and the Solvent on the Reaction Rate.
✍ Scribed by Maria E. Gonzalez-Nunez; Jorge Royo; Rossella Mello; Minerva Baguena; Jaime Martinez Ferrer; Carmen Ramirez de Arellano; Gregorio Asensio; G. K. Surya Prakash
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Reactions of isopropyl and of undecyl radicals with __meta‐__ and __para__‐substituted toluenes are reported. The results demonstrate that the reactivities of toluenes are due to both benzyl‐H abstraction and addition of the alkyl radicals to the aromatic ring. Relative reactivities yie
## Abstract The bond‐formation processes between the d^10^ metal fragments Ni(PR~3~)~2~ (R = H, CH~3~, F, CF~3~, Ph) and acetylene have been studied by density functional theory with the BP86 functional and large TZV(2df,2pd) basis sets. The Ni–acetylene bonds have been analyzed in terms of distort