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Oxygenation of (3Z)-Alkenals to 4-Hydroxy-(2E)-Alkenals in Plant Extracts: A Nonenzymatic Process

✍ Scribed by Minke A. Noordermeer; Ivo Feussner; Adelheid Kolbe; Gerrit A. Veldink; Johannes F.G. Vliegenthart


Book ID
115586721
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
162 KB
Volume
277
Category
Article
ISSN
0006-291X

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Molecular oxygen trapping reaction of alkenes with 2,3-pyrrolidinedione derivatives was developed using a Mn(lll)-induced oxidation system. AIkenes and 2,3-pyrrolidinediones were treated with manganese(Ill) acetate in acetic acid under a stream of dry air, giving l-hydroxy-8-aza-2,3-dioxabicyclo[4.3