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Oxygen Tracer Studies on the Reaction of Cyanate Ion with Aquo and Diaquo Cobalt Ammines, and on the Nitrosation of Carbamatopentaamminecobalt(III)

✍ Scribed by Sargeson, Alan M.; Taube, Henry


Book ID
126257597
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
819 KB
Volume
5
Category
Article
ISSN
0020-1669

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## Abstract Treatment of 3‐aryl‐2‐thioxo‐1,3‐thiazolidin‐4‐ones **1** with CN^−^ and NCO^−^ effected the ring cleavage providing [(cyanocarbonothioyl)amino]benzenes **4** and arylisothiocyanates **5**, respectively. Similar treatment of 5‐(2‐aryl‐2‐oxoethyl) derivatives **2** afforded 2,4‐bis(2‐ary