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Oxygen Stoichiometry in BaRE(Cu0.5Fe0.5)2O5+δCompounds with Perovskite or Double Perovskite Structure

✍ Scribed by K. Peitola; M. Kochi; M. Karppinen; H. Yamauchi; L. Niinistö; J. Lindén

Book ID
110421508
Publisher
Springer US
Year
1999
Tongue
English
Weight
239 KB
Volume
117
Category
Article
ISSN
0022-2291

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Interplay between Cu and Fe Valences in
Interplay between Cu and Fe Valences in BaR(Cu0.5Fe0.5)2O5+δ Double Perovskites with R=Lu, Yb, Y, Eu, Sm, Nd, and Pr
✍ J. Lindén; M. Kochi; K. Lehmus; T. Pietari; M. Karppinen; H. Yamauchi 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 389 KB

We have conducted a systematic 57 Fe MoK ssbauer study on BaR(Cu 0.5 Fe 0.5 ) 2 O 5؉ double perovskites with various oxygen contents and rare-earth elements (R ‫؍‬ Lu, Yb, Y, Eu, Sm, Nd, and Pr). In samples based on R ‫؍‬ Lu, Yb, Y, Eu, Sm the oxygen content remained at +0, upon reductive or oxidati