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Oxygen permeability of electron beam cured gelatin methacrylate layers

โœ Scribed by Tom Scherzer; Rolf Schubert


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
199 KB
Volume
9
Category
Article
ISSN
1042-7147

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โœฆ Synopsis


The oxygen permeability of electron beam cured layers of gelatin methacrylate was studied. Gelatin coatings on various polymer foils or paper were found to have excellent gas barrier properties. The influence of factors such as the substrate material, the coating thickness and the composition of the gelatin formulation on the permeability was investigated. Moreover, the water vapor transmission of gelatin layers was determined. Their high moisture permeation can only be reduced by an additional barrier layer against water vapor. Laminates were prepared of polymer films and/or paper using the methacrylated gelatin as barrier and adhesive layer. Such laminates show very low permeabilities for oxygen and water vapor. If substrate foils of biodegradable polymers are used, completely biodegradable laminates with a reasonable oxygen transmission can be made.


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Gelatin was chemically modified with different amounts of glycidyl methacrylate. The methacrylated gelatins were crosslinked by electron irradiation. The resulting solid polymer-like coatings were analytically characterized with respect to the content of residual double bonds and the amount of extra