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Oxygen non-stoichiometry and defect equlibria in CaMnO3 − δ

✍ Scribed by Ekaterina I. Goldyreva; Ilya A. Leonidov; Mikhail V. Patrakeev; Victor L. Kozhevnikov

Book ID
113053637
Publisher
Springer
Year
2011
Tongue
English
Weight
163 KB
Volume
16
Category
Article
ISSN
1432-8488

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Study of La1−xMnO3−δnon-stoichiometry an
Study of La1−xMnO3−δnon-stoichiometry and defect structure using ESR and iodometry
✍ M. Ippommatsu; S. Otoshi; H. Sasaki; H. Ohnishi; T. Higuchi; M. Miyayama; H. Yan 📂 Article 📅 1993 🏛 Springer 🌐 English ⚖ 295 KB

The oxidation states of manganese in the Lal\_xMnO3\_~ (x--0.09-0.11) were investigated by electron spin resonance (ESR) and iodometry. The ESR analysis carried out at room temperature for the samples prepared in air revealed the presence of broad peaks at g = 2.0, considered to be relevant to Mn 2