✦ LIBER ✦

Oxygen-NO2 energy transfer

✍ Scribed by R.J. O'Brien Jr.; G.H. Myers

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 214 KB
Volume: 9
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)85120-5

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✦ Synopsis

Tile r:ltc of production of NOB by energy transfer from tional to [02(l$J] singlet molecular oxygen is showr. to be propor-~YCII under conditione where [O~(~xa] IS not proportional to [02(lAa)]". This helps establish Z = k[O2('$)] [02( b )I INOB] 3s the rate law for the 0; + NO2 energy transfer process. Evidcncc for cncrgy transfer from N & 2 to O2 is reported. Excitation of NO2 by energy transfer from 05 was first reported by Bader and Ogryzlo [II. Arnold [2] has established that ZNO~ a [O,( lAg)j3 in a discharge flow system. This rate law is consistent with an overall reacti& of either 302&d + NO2 -NO; + 302

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