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Oxygen isotope exchange between O2 adsorbate and UV-irradiated MgO surfaces

โœ Scribed by Y. Yanagisawa; R. Huzimura; K. Matsumura; S. Yamabe


Publisher
Elsevier Science
Year
1991
Weight
70 KB
Volume
242
Category
Article
ISSN
0167-2584

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Studies on the rate of isotopic oxygen e
โœ Fred F. Kashani; R. Kent Murmann ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 479 KB ๐Ÿ‘ 1 views

The rate of oxygen exchange between truns-[Re(py),02]+ and solvent water in py-pyH' buffer solution follows simple first-order kinetics and both oxygens are equivalent. The half-life for isotopic oxygen exchange is about 12 h at a pH of 5.0, 25"C, and [pyl = 0.10 M. The observed rate constant for ex