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Oxygen exchange between CO and CO2

โœ Scribed by C.A. Bank; E.A.Th. Verdurmen

Book ID
118904958
Publisher
Elsevier Science
Year
1963
Weight
384 KB
Volume
25
Category
Article
ISSN
0022-1902

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A study was made of the reversible exchange of oxygen between CO a and CO on a carbon kl surface, CO 2+ CfeCO+ Co, at 750"-850ยฐC and atmospheric pressure with carbon-14 used as a tracer. At these temperatures the rates of exchange were a few orders of magnitude greater than the rates of gasification

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19 torr and a flow rate of 1.4 x 10'" was 2.71 x 10" atoms of C per cm" per sec. This is 1.8 per cent of the rate of ablation of graphite with oxygen for similar reaction conditions. The effect of pressure, flow and temperature on the rate of reaction is presented. Correlation is made with kinetic t