Based on a model by Ba~ant and Najjar, and using a new model for adsorption isotherms, moisture capacity and diffusivity of concrete are analyzed. The moisture capacity, obtained as a derivative of the adsorption isotherm, first drops as the humidity increases from zero, then levels off as a constan
Oxygen diffusivity of various cementitious materials
β Scribed by Kazusuke Kobayashi; Keizoh Shuttoh
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 567 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0008-8846
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β¦ Synopsis
In order to quantitatively grasp the diffusivity of oxygen in concrete, an apparatus for measuring the amount of oxygen permeating through concrete due to a concentration gradient under a condition of constant pressure was manufactured on a trial basis.
Next, using this apparatus, the oxygen diffusion coefficients of vari6us cementitlous materials of different mix proportions, curing conditions, and moisture contents were measured, and it was shown that the oxygen diffusion coefficient of mortar is considerably lower than that of concrete, and by intermixing a polymer dispersion in the mortar, the value of the oxygen diffusion coefficient could be made markedly lower.
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This article describes an improvement on a previous model proposed by Ba~ant and Najjar, in which moisture diffusivity and moisture capacity are treated as separate parameters. These parameters are evaluated from independent test results, and are shown to depend on the water:cement ratio, curing tim
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