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Oxygen Diffusion into Latex Films Annealed at Various Temperatures: A Fluorescence Study

✍ Scribed by Ö Pekcan; Ş Uğur


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
100 KB
Volume
217
Category
Article
ISSN
0021-9797

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✦ Synopsis


A simple fluorescence technique is proposed for the measurement of the diffusion coefficient of oxygen into latex films. These latex films were prepared by annealing pyrene (P) labeled polymethyl methacrylate (PMMA) particles above the glass transition temperature. Transparency of these films were measured by monitoring the transmitted photon intensity, I tr , which increased as the annealing temperature was increased. Steady state fluorescence was used to monitor oxygen diffusion into latex films. Diffusion coefficients, D, of oxygen were determined using fluorescence quenching method and are found to be around 5.6 ؋ 10 ؊11 cm 2 s ؊1 .