Oxygen Complexes and Oxygen Activation by Transition Metals

✍ Scribed by F. Basolo (auth.), Arthur E. Martell, Donald T. Sawyer (eds.)

• Publisher: Springer US
• Year: 1988
• Tongue: English
• Leaves: 340
• Edition: 1
• Category: Library

✦ Synopsis

This monograph consists of manuscripts, summary statements, and poster abstracts submitted by invited speakers and poster contributors who participated in the symposium "Oxygen Complexes and Oxygen Activation by Transition Metals," held March 23-26, 1987, at Texas A&M University. This meeting was the fifth annual international symposium sponsored by the Texas A&M Industry-University Cooperative Chemistry Program (IUCCP). The co­ chairmen of the conference were Professors Arthur E. Martell and Donald T. Sawyer of the Texas A&M University Chemistry Department. The program was developed by an academic-industrial steering committee consisting of the co-chairmen and members appointed by the sponsoring chemical companies Dr. James F. Bradzil, The Standard Oil Company, Ohio; Dr. Jerry R. Ebner, Monsanto Company; Dr. Craig Murchison, Dow Chemical Company; Dr. Donald C. Olsen, Shell Development Company; Dr. Tim R. Ryan, Celanese Chemical Company; and Dr. Ron Sanderson, Texaco Chemical Company. The subject of this conference reflects the intense interest that has developed in academic institutions and industry on several aspects of dioxygen chemistry. These include the formation of dioxygen complexes and their applications in facilitated transport and oxygen separation; homo­ geneous and heterogeneous catalysis of oxidation; and oxygenation of organic substrates by molecular oxygen. The conference differs in two respects from several other symposia on dioxygen chemistry held during the past few years. First, there is extensive industrial participation, especially with respect to oxygen activation.

✦ Table of Contents

Front Matter....Pages i-ix
Opening Remarks....Pages 1-2
Bonding of Dioxygen to Transition Metals....Pages 3-16
Oxygen Binding by the Metalloproteins Hemerythrin, Hemocyanin, and Hemoglobin....Pages 17-32
Metal Oxo Complexes and Oxygen Activation....Pages 33-47
Kinetics of Formation of Biological Oxygen Carriers....Pages 49-60
Synthetic Dioxygen Carriers for Dioxygen Transport....Pages 61-85
Formation and Degradation of Cobalt Dioxygen Complexes....Pages 87-106
Reversible Complexes for the Recovery of Dioxygen....Pages 107-125
Summary — Dioxygen Complexes with Transition Metal....Pages 127-128
Summary — Oxygen Activation by Transition Metals....Pages 129-130
The Chemistry and Activation of Dioxygen Species (O 2 , O 2 -. , and HOOH) in Biology....Pages 131-148
Oxygen Activation by Neutrophils....Pages 149-174
Mechanisms of Dioxygen Activation in Metal-Containing Monooxygenases: Enzymes and Model Systems....Pages 175-187
Radical Cation Pathways for Selective Catalytic Oxidation by Molecular Oxygen....Pages 189-201
Vanadium Catalyzed Autoxidation of Hydrogen Sulfide....Pages 203-213
Copper Catalyzed Oxidative Carbonylation of Methanol to Dimethyl Carbonate....Pages 215-232
Dependence of Reaction Pathways and Product Distribution on the Oxidation State of Palladium Catalysts for the Reactions of Olefinic and Aromatic Substrates with Molecular Oxygen....Pages 233-251
Oxygen Activation and Oxidation Reactions on Metal Surfaces....Pages 253-264
Methane Oxidation at Metal Oxide Surfaces....Pages 265-272
The Activation of Oxygen by Metal Phosphorus Oxides — The Vanadium Phosphorus Oxide Catalyst....Pages 273-292
The Oxidation of Organic Compounds by Metal Complexes in Zeolites....Pages 293-303
Front Matter....Pages 305-305
Kinetics and Mechanisms of Degradation of Binuclear Cobalt Dioxygen Complexes....Pages 307-307
Methane Activation Over Lanthanide Oxides....Pages 308-308
Dioxygen Affinities of Some Synthetic Cobalt Schiff Base Complexes....Pages 309-309
Temporal Analysis of Products (TAP): A Unique Catalyst Evaluation System with Sub-Millisecond Time Resolution....Pages 310-310
Dioxygen Insertion into Metal-Carbon Bonds of Metalloporphyrins: Formation and Characterization of Alkylperoxy Metalloporphyrins....Pages 311-311
Iron Porphyrin Catalyzed Air Oxidation of Aldehydes and Alkenes....Pages 312-312
Oxidative Dimerization of Methane Over Sodium-Promoted Calcium Oxides....Pages 313-313
Synthesis and Metal Ion Affinities of a Binucleating Polyamine: Reversible Formation of a Cobalt Dioyxgen Complex....Pages 314-314
Potentiometric Determination of Stabilities of Cobalt(II) Complexes of Polyamine Schiff Bases and Their Dioxygen Adducts....Pages 315-315
Catalysis of Cobalt Schiff Base Complexes for the Oxygenation of Olefins. Mechanisms for the Ketonization Reaction....Pages 316-318
Selective Oxidation of Saturated Hydrocarbons by the Gif and Gif-Orsay Systems....Pages 319-319
The Formation, Characterization, and Reactivity of the Oxene Adduct of Tetra-Kis(2,6-Dichlorophenyl)Porphinato-Iron(III) Perchlorate in Acetonitrile....Pages 320-320
Preparation and Characterization of A Binuclear Iron(III)-Hydroxo-µ-Hydroxyperoxy Complex(PH 3 PO) 4 (HO)Fe III (HOOH)Fe III (OH)(OPPh 3 ) 4 4 ....Pages 321-321
Autoxidation of Fe II (Dihydroxyphenanthroline) 3 ....Pages 322-322
Phosphine-Ruthenium(II)-Aquo Redox Chemistry: The Aerobic Catalytic Oxidation of Cyclohexene....Pages 323-323
The Oxidation of Organic Substrates By Molecular Oxygen; Catalysis By Ru(III) And Ru(III)-Edta....Pages 324-325
Oxygenation of Tryptophane Catalyzed by Polyamine Cobalt Dioyxgen Complexes....Pages 326-326
Resonance Raman Spectroscopy of the Fe(IV)=O Group in Peroxidase Intermediates....Pages 327-327
Reaction of Dioxygen with Synthetic Copper(I) Compounds of Biological Relevance....Pages 328-328
Front Matter....Pages 305-305
Thorough Elucidation of Oxygenation- and Oxidation-Mechanisms of Iron(II) Porphyrin on the Basis of a New Hypothesis for an Electron-Transfer Pathway....Pages 329-330
Back Matter....Pages 331-341

✦ Subjects

Biochemistry, general