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Oxygen-18 scrambling studies in the solvolysis of benzyl tosylates

โœ Scribed by Yutaka Tsuji; Sung Hong Kim; Yoshihiro Saeki; Ken-ichi Yatsugi; Mizue Fujio; Yuho Tsuno

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
235 KB
Volume
36
Category
Article
ISSN
0040-4039

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Solvolysis of (o-, m-and p-carboranyl)benzyl toluene-p-sulfonates substituted at the second carbon atom with a phenyl group bearing a range of substituents at the para position has been performed. The rates of hydrolysis of m-and p-carboranyl derivatives measured linearly with increasing electron-re