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Oxygen-17 quadrupole coupling in liquid acetone

✍ Scribed by B. H. Ruessink; C. Maclean

Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
311 KB
Volume
25
Category
Article
ISSN
0749-1581

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✦ Synopsis

0 NMR spectroscopy of liquid acetone, oriented in a strong applied electric field, was used to measure one of the principal components of the I7O quadrupole coupling tensor (qct). The component along the carbonyl bond was found to be (*)3.0*0.2 MHz. By comparison with other data in the literature concerning acetone and related molecules, it can be concluded that this value refers to the smallest of the principal components. The proposed NMR method is a powerful technique for obtaining information about qcts in normal liquids.

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