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Oxygen-17 nuclear magnetic resonance chemical shifts of dialkyl peroxides: large conformational effects

✍ Scribed by Zagorski, Michael G.; Allan, David S.; Salomon, Robert G.; Clennan, Edward L.; Heah, Poh Choo; L'Esperance, Robert P.

Book ID
126469280
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
850 KB
Volume
50
Category
Article
ISSN
0022-3263

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Oxygen-17 and Carbon-13 Nuclear Magnetic
Oxygen-17 and Carbon-13 Nuclear Magnetic Resonance. Chemical shifts of unsaturated carbonyl compounds and acyl derivatives
✍ Claude Delseth; Thi Thanh-tΓ’m NguyΓͺn; Jean-Pierre Kintzinger πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 German βš– 324 KB

## Abstract The ^17^O and ^13^C chemical shifts (Ξ΄) of 14 Ξ±,β‐unsaturated aldehydes and ketones and 33 acyl derivatives RXC = O (X = Cl, OH, OMe, OEt, NH~2~ and R = H or alkyl) have been measured. In the unsaturated carbonyl series, a correlation exists between Ξ΄ ^17^O and the Ο€ electron density at