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Oxygen-17 NMR studies of N-nitrosamines

✍ Scribed by Giovanni Cerioni; Angelo G. Giumanini; Giancarlo Verardo; Hans Dahn

Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 472 KB
Volume: 32
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260320110

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✦ Synopsis

Abstract

Natural abundance ^17^O NMR data for seven aliphatic, nine cyclic and thirteen aromatic N‐nitrosamines, recorded at room temperature in acetonitrile, are reported. Differences in chemical shifts among and within the three groups are discussed in terms of electronic and steric effects. The σ^+^ value for the N‐nitrosamine group was estimated. A comparison between amides and N‐nitrosamines was made.

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