Oxone as oxygen donor in the catalytic hydroxylation of saturated hydrocarbons
β Scribed by Bertha De Poorter; Marco Ricci; Bernard Meunier
- Book ID
- 104222198
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 212 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
## Abstract The catalytic hydrogenation of [2.2]paracyclophane 1 has been reinvestigated with the following results: a) Best yields (95%) of the perhydrocyclophane 3 are obtained when 1 is hydrogenated over ruthenium on charcoal in ethanol at 200Β°C and 300 atm in the presence of lithium hydroxide;
The reaction rates and selectivity of lower olefines formation in high temperature reactions, such as catalytic methane dehydrodimerization and catalytic pyrolysis of C, hydrocarbons are substantialy enhanced by oxygen and oxygen-containing compounds.