Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones

✍ Scribed by Sharada R. Girish; Vidyanand K. Revankar; Vinayak B. Mahale

• Book ID: 104638757
• Publisher: Springer
• Year: 1996
• Tongue: English
• Weight: 388 KB
• Volume: 21
• Category: Article
• ISSN: 0340-4285
• DOI: 10.1007/bf00140779

✦ Synopsis

Oxomolybdenum(V) complexes of general formulae [MozO3L2Clz]HaO and [MozO3La(OH)z(H=O)z] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5bromo-, 3-methoxysalicyldehyde and 2-hydroxy-l-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments, thermal studies, and i.r., u.v.-vis, and e.p.r, spectra. The data suggest that the complexes are non-electrolytes, paramagnetic and have distorted octahedral structures with possible metal-metal interactions via oxo bridging.