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Oxiranyl Anions in Organic Synthesis: Application to the Synthesis of Hemibrevetoxin B

✍ Scribed by Mori, Yuji; Yaegashi, Keisuke; Furukawa, Hiroshi

Book ID: 127079902
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 224 KB
Volume: 119
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja9701523

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Exploitation of molecular symmetry can greatly improve the efficiency of syntheses. The symmetry embedded in the centrosymmetric AB dioxepane fragment of hemibrevetoxin B was exploited for the first time in the preparation of an established intermediate in its total synthesis. Desymmetrization of th