Oxidized states of methoxy- and hexyl-oligothiophenes with ferrocenyl groups
β Scribed by Masa-Aki Sato; Kazuhiko Fukui
- Book ID
- 116898242
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 676 KB
- Volume
- 157
- Category
- Article
- ISSN
- 0379-6779
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π SIMILAR VOLUMES
## Abstract Liquid crystalline (LC) polymers with monosubstituted ferrocenyl units in the side chain were prepared by radical polymerizations of the corresponding LC and nonβLC acrylates. It was demonstrated that polymerization is useful for the LC orientation and expands the LC temperature range.
Oxidation of alkyl phenyl tellurides and telluroxides with meta-chloroperbenzoic acid in methanol at room temperature afforded the corresponding alkyl methyl ethers in high yields. The reaction was accompanied by phenyl migration and ring-contraction respectively when applied to the compounds havin