Oxidisability of environmental sulphur under different catalytic conditions

✍ Scribed by Namrata Shukla; G. S. Pandey

• Book ID: 104640982
• Publisher: Springer Netherlands
• Year: 1993
• Tongue: English
• Weight: 343 KB
• Volume: 15
• Category: Article
• ISSN: 1573-2983
• DOI: 10.1007/bf00146292

✦ Synopsis

The oxidation of elemental sulphur in the catalytic presence of selected metal ions [Cr(III), Ce(III), Cu(II), Hg(II), Ni(II), Co(II), Mo(VI), Cd(II), Zn(II), Ti(IV), and V(V)], and hydrocarbons (benzene, gasoline, and kerosene) was studied in an alkaline medium buffered by marble powder. The catalytic efficiencies of metal ions were: Cr(III) > Ce(III) > Cu(II) > Hg(II) > Ni(II). The oxidation process was inhibited in the presence of other ions, and the inhibitive effect was in the following order: Co(II) < Mo(VI) < Cd(II) < Zn(II) < Ti(IV) < V(V). In the case of hydrocarbons, the efficiencies were as follows: gasoline > benzene > kerosene. The oxidation of sulphur in sulphur-loaded soils obtained from near a textile mill and a distillery were also carried out in the c both cases was significantly enhanced.