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Oxidimetric determination of indigo with iron(III) and hexacyanoferrate(III)

✍ Scribed by G.Gopala Rao; V. Rukmini


Book ID
118990253
Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
243 KB
Volume
14
Category
Article
ISSN
0039-9140

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Iron(lll) hexacyanoferrate(lll) is shown to be a useful reagent in oxidative coupling of 4,5,5,. Dimerisation proceeds via oxidative demethylation and loss of chloride to give an orrho-quinonoid dimer in high yield. The proposed structure 1 is based largely on mass-spectra of methyl derivatives of t