𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Oxide ion electrodes and oxide ion donors in molten alkaline halogenides. A consideration of potentiometric studies

✍ Scribed by V.L. Cherginets

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
770 KB
Volume
42
Category
Article
ISSN
0013-4686

No coin nor oath required. For personal study only.

✦ Synopsis

Literature data on reversibility of gas, metal-oxide and membrane ZrO2(Y203 or CaO) oxygen electrodes have been considered together with the obtained data for molten alkaline halogenide melts. An explanation of the existence of two slopes for Pt-based electrodes has been proposed. A metal-oxide and a membrane electrodes have been used for studies of dissociation of some oxide-ion donors in molten alkaline halogenides in order to check the completeness of dissociation. NaOH and BaO have been found to be completely dissociated bases in molten chlorides, CO:-ion was a strong, but incompletely dissociated base. Dissociation of BaO became incomplete in molten bromides.

πŸ“œ SIMILAR VOLUMES

Potentiometric acid-base titrations in m
Potentiometric acid-base titrations in molten saltsβ€”IV. Basic character of some oxide-ion donors in molten KNO3: their reaction with NaPO3 and K2Cr2O7
✍ A.M. Shams El Din; A.A. El Hosary πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 English βš– 989 KB

The basic character of electrogenerated O\*-, OH-, OS\*-, COIs-, HCO,-, HCOO-, (COO),\*-and CH.C!OO-in fused KNOs at 350Β°C was studied by forward and backward potentiometric neutralization experiments with the two acids NaPOI and K,Cr,O,. The anions fall into two distinct groups. To the first, the "

A chronopotentiometric study of the stab
A chronopotentiometric study of the stability of oxide ion in molten nitrates
✍ A.A. El Hosary; A.M. Shams El Din πŸ“‚ Article πŸ“… 1971 πŸ› Elsevier Science 🌐 English βš– 568 KB

The chronopotentiometric behaviour of NaNO,-KNO\* melts made basic with OH-, 04\*-or electrogenerated Oa-has been studied in the temperature range 240-350Β°C. The anodic curves exhibit two diffusion-controlled steps corresponding to the reactions and 10z-j -2e-c+0, NO,--e 4 NO,. Oxygen evolution from

Electrochemical study of the anodic oxid
Electrochemical study of the anodic oxidation of nitrate ion on a platinum electrode in acetic acid
✍ M. Colombi; G. Fiori; L. Formaro πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science βš– 190 KB

Various authors 1-3 suggest that nitrate radicals can play an important role as intermediates in the electrochemical oxidation of aromatic hydrocarbons. The direct oxidation of NO 3 ions in non-aqueous solvents has been examined by other authors 4-6 and two different pathways have been proposed: sch