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Oxidative ring opening of furan derivatives to α,β-unsaturated γ-dicarbonyl compounds, useful intermediates for 3-oxocyclopentenes synthesis

✍ Scribed by G. Piancatelli; A. Scettri; M. D'Auria


Book ID
107857164
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
242 KB
Volume
36
Category
Article
ISSN
0040-4020

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## Abstract A new cascade pathway viable for Knoevenagel chemistry that involves the coupling between 1,3‐dicarbonyl systems and α,β,γ,δ‐unsaturated aldehydes has been developed. The process comprises the combination of a classic aldol‐type condensation and a rare spontaneous metal‐free cycloisomer