Oxidative Rearrangement Processes in the Biosynthesis of Gilvocarcin V
✍ Scribed by Liu, Tao; Fischer, Carsten; Beninga, Claus; Rohr, Jürgen
- Book ID
- 126223902
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 53 KB
- Volume
- 126
- Category
- Article
- ISSN
- 0002-7863
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## Abstract __During the biosynthesis of certain tropane alkaloids, littorine (**1**) is rearranged to hyoscyamine (**3**). Recent evidence indicates that this isomerisation is a two‐step process in which the first step is an oxidation/rearrangement to give hyoscyamine aldehyde (**2**). This step i