𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Oxidative rearrangement of trismethylene-trinitrobenzene: Nucleophilic aromatic addition VI

✍ Scribed by Th. J. de Boer; J. C. van Velzen


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
427 KB
Volume
83
Category
Article
ISSN
0165-0513

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


The structural proof of trismethylene-tr
✍ Th. J. de Boer; J. C. van Velzen 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 580 KB

## Abstract “Trismethylene‐trinitrobenzene” has structure IV and not VI (chart 1) as shown by ozonolysis, yielding an aldehydic acid VIII, a dicarboxylic acid IX and, on decarboxylation, a __mono__carboxylic acid X (chart 2). Ozonolysis in methanol leads to products which are consistent with the me

Distribution of radio activity in trisme
✍ Th. J. de Boer; J. C. van Velzen 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 149 KB

## Abstract The previously suggested mechanism for the formation and the stepwise degradation of “trismethylene‐trinitrobenzene” (I) is confirmed by application of a ^14^C tracer technique. It is shown that all transformations occur without hydrogen shift. In this paper besides compound II a stere

Nucleophilic aromatic addition: I. The r
✍ Th. J. de Boer; J. C. van Velzen 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 703 KB

## Abstract The structure of the reaction product from 1,3,5‐trinitrobenzene and an excess (i.e. at least four moles) of diazomethane, as found many years ago by __Heinke__, is shown to be a seven‐membered ring‐compound condensed with two cyclopropane rings and with one pyrazoline ring (VII). If 1,