Oxidative properties of xenon (II) compounds. A new, convenient synthesis of [bis(trifluoroaceteoxy)iodo]arenes, [bis(trifluoroacetoxy)iodo]perfluoroalkanes and μ-oxo-bridged aryliodoso-derivatives.

✍ Scribed by Tahir M. Kasumov; Valery K. Brel; Yuri K. Grishin; Nikolai S. Zefirov; Peter J. Stang

• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 430 KB
• Volume: 53
• Category: Article
• ISSN: 0040-4020
• DOI: 10.1016/s0040-4020(96)01044-7

✦ Synopsis

The osldatlre propertIes of xenon bis(tnfluoroacctate) relative to aryl-and perfluoroalkyliodide w-ere studled. The interesting fcaturc of the rcactlon IS the formation of the lodosocsters of trifluoroacetate or their l_t-oxo-dcrivativcs. Copyright 0 1996 Elsevier Sc~encc Ltd There is great current interest in the chemistry of aryliodine(lIl) dicarboxylates (AID) ' They are widely used in organic synthesis as efficient oxidants,'. * acetoxylating' and aryliodinating reagents.' Considerable effort has been devoted to the search for new methods of synthesis and structure investigation of AIDS.'.' To