Ortho-, meta-, and para-phenylenediamines were polymerized using hydrogen peroxide as an oxidant and horseradish peroxidase as a catalyst in mixed solvents of 1,4-dioxane and water. The yield of the polymers was strongly dependent on solvent composition, and maximum yields were obtained at 15-30% 1,
Oxidative polymerization of phenylenediamines in reversed micelles
β Scribed by Daigo Ichinohe; Norihiro Saitoh; Hideo Kise
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 480 KB
- Volume
- 199
- Category
- Article
- ISSN
- 1022-1352
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Oxidative polymerization of m-phenylenediamine was carried out using H 2 O 2 as an oxidant and horseradish peroxidase as a catalyst in mixtures of aqueous buffer solution and 1,4-dioxane or in reversed micellar solutions. When the reaction mixture was brought into contact with a stainless steel stic
Deactivation data and fluorescence intensity changes were used to probe functional and structural stability of cutinase in reverse micelles. A fast deactivation of cutinase in anionic (AOT) reverse micelles occurs due to a reversible denaturation process. The deactivation and denaturation of cutinas