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Oxidative polymerization of N-substituted carbazoles

✍ Scribed by A. Sezai Sarac; Esma Sezer; Belkis Ustamehmetoglu

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
481 KB
Volume
8
Category
Article
ISSN
1042-7147

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✦ Synopsis

Poly (N-vinylcarbazole), poly(N-carbazole) and poly(Nethylcarbazole) powders were chemically synthesized by the reaction of ceric ammonium nitrate (CAN) with N-vinylcarbazole carbazole and N-ethylcarbazole in acetonitrile. Products were characterized by elemental analysis, Fourier transform infrared spectroscopy, scanning electron microscopy and viscosity, X-ray fluorescence and four-probe conductivity measurement. It is found that when a suitable concentration of CAN is used in the polymerization process, the conductivity of chemically synthesized polymers can be improved further by controlling the CAN addition.

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