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Oxidative nucleophilic substitution of hydrogen by primary amines in 2-nitrobenzo[b]thiophene

โœ Scribed by Sheetal S. Surange; Srinivasachari Rajappa


Book ID
104259875
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
170 KB
Volume
39
Category
Article
ISSN
0040-4039

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Oxidative nucleophilic substitution of h
โœ Mieczysล‚aw Mฤ…kosza; Marek Surowiec ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 158 KB

Enolates generated by treatment of silyl ketene acetals and enol ethers with fluoride ion sources add to nitroarenes to produce s H adducts that oxidize either with KMnO 4 to give substituted nitroarenes or with dimethyldioxirane to give substituted phenols. In the latter case the oxidation results