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Oxidative kinetic resolution of 1-phenylethanol catalyzed by sugar-based salen–Mn(III) complexes

✍ Scribed by Furong Han; Jiquan Zhao; Yuecheng Zhang; Weiyu Wang; Yanyan Zuo; Junwei An

Book ID: 108080533
Publisher: Elsevier Science
Year: 2008
Tongue: English
Weight: 155 KB
Volume: 343
Category: Article
ISSN: 0008-6215
DOI: 10.1016/j.carres.2008.04.022

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## Abstract Catalytic properties of a series of chiral (pyrrolidine salen)Mn(III) complexes for asymmetric oxidation of aryl methyl sulfides were evaluated. Moderate activity, good chemical selectivity and low enantioselectivity were attained with iodosylbenzene as a terminal oxidant. Enantioselect