Oxidative Isomerization of Vinylidenecyclopropanes to Dimethylenecyclopropanes and Brønsted Acid-Catalyzed Further Transformation
✍ Scribed by Bei-Li Lu; Min Shi
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 885 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-193X
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## Abstract The perchlorate salt of the dicationic bipy–ruthenium complex __cis__‐[Ru(6,6′‐Cl~2~bipy)~2~(H~2~O)~2~]^2+^ effectively catalyzes addition of β‐diketones to secondary alcohols and styrenes to yield the α‐alkylated β‐diketones. In a catalytic addition reaction of acetylacetone to 1‐pheny