Organochromium complexes, [CrRL(H20)] 2 Β§ (L= 1,4,8,12-tetraazacyclopentadecane; R = 1 ~ or 2~ or para-substituted benzyl), are oxidized to [CrRL(H 20)] 3 +, which rapidly decomposes (k 3 > 102 s-1) by homolysis of the Cr--C bond. Rate constants of the oxidation of these complexes by [IrC16] 2-range
β¦ LIBER β¦
Oxidative Homolysis of a Nitrosylchromium Complex
β Scribed by Wenjing Song; Andreja Bakac
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 276 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Oxidative homolysis of organochromium(II
β
Shu Shi
π
Article
π
1994
π
Springer
π
English
β 317 KB
Homolysis of N-alkoxyamines: A Computati
β
Anouk Gaudel-Siri; Didier Siri; Paul Tordo
π
Article
π
2006
π
John Wiley and Sons
π
English
β 268 KB
π 1 views
## Abstract __During nitroxideβmediated polymerization (NMP) in the presence of a nitroxide R__^2^__(R__^1^__)NO^.^, the reversible formation of__ N__βalkoxyamines [Pο£ΏON(R__^1^__)R__^2^__] reduces significantly the concentration of polymer radicals (P^.^) and their involvement in termination reacti
Electrochemical Study of CIS-Dicyanoaquo
β
Miroslav Rievaj; Elena KorgovΓ‘; Dusan Bustin
π
Article
π
2010
π
Wiley (John Wiley & Sons)
β 273 KB
π 1 views
Mechanistic aspects of homolysis of a se
β
A.K. Yatsimirsky; O.I. Kavetskaia; I.I. Levitin; M.E. Vol'pin
π
Article
π
1989
π
Elsevier Science
π
English
β 70 KB
Modeling complexity of a complex gate ox
β
Alexander A. Demkov; O. Sharia; X. Luo; G. Bersuker; J. Robertson
π
Article
π
2009
π
Elsevier Science
π
English
β 777 KB
A Dramatic Push Effect on the Homolysis
A Dramatic Push Effect on the Homolysis of FeIII(OOR) Intermediates To Form Non-Heme FeIVO Complexes
β
JΓ³zsef Kaizer; Miquel Costas; Lawrence Que Jr.
π
Article
π
2003
π
John Wiley and Sons
π
English
β 132 KB