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Oxidative fragmentation of 9-aminomethylacridan

โœ Scribed by George A. Digenis; H. W. Whitlock Jr.


Book ID
102914731
Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
579 KB
Volume
61
Category
Article
ISSN
0022-3549

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Previously we have reported an unusual oxidative amine fragmentation of 9-aminomethylacridan (g-AMA) (I) to acridine (II) (Eq. 1) by pyridoxal', sodium 1,2-napthoquinone-4sulfonate, and nitrous acid\*. Drawing upon our previous data 132 , we proposed a mechanism for the formation of acridine through

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