Oxidative fluorination of sulfur(IV) compounds by XeF2
β Scribed by Alexander F. Janzen; Xiaobo Ou
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 62 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0022-1139
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Electrochemical fluorination of chlorobenzene (1) in neat Et,NF mHF (Et = C,H, : m = 4.0, 4.45 and 4.7) was carried out on a platinum anode at 2.3 or 2.5 V vs. Ag/Ag' (0.01 M; M = mol dme3). As the primary products, I-chloro-2-fluorobenzene (2) and 1-chloro-4-fluorobenzene (3) were obtained, whose
## Abstract In the Ni(II)βS(IV)βO~2~ system in the region of pH > 8.4, both Ni(II) and S(IV) are simultaneously autoxidized, and when sulfur is consumed fully NiOOH precipitates. At pH > 8.4, ethanol has no effect on the rate, whereas ammonia strongly inhibits the reaction when pH > 7.0. The kineti