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Oxidative DNA Cleavage by Free and Oligonucleotide-Conjugated O-Bromobenzoic Acid in the Presence of Copper(II) Ions

✍ Scribed by O. A. Koval; S. B. Oleinikova; V. V. Litvak; V. V. Vlassov; E. I. Chernolovskaya

Publisher: John Wiley and Sons
Year: 2005
Weight: 9 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200505202

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## Abstract The reaction of 2,4,6‐tri(pyridyl)‐1,3,5‐triazine (ptz) and copper(II) salts in dmf/water (1:1) results in the hydrolysis of ptz and formation of the anions bis(2‐pyridylcarbonyl)amide (ptO~2~^–^) and bis(2‐pyridylamine)amide (ptN~2~^–^), which are found in the complexes [Cu(ptN~2~)(OAc