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Oxidative dimerization of heterocyclic nitrones, derivatives of pyrroline and imidazoline

โœ Scribed by V. A. Reznikov; V. V. Martin; L. B. Volodarskii

Book ID
112449491
Publisher
Springer
Year
1990
Tongue
English
Weight
534 KB
Volume
39
Category
Article
ISSN
1573-9171

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The reaction of [3-oxonitrones --imidazoline derivatives --with hydroxylamine, phenylhydrazine, and semicarbazide takes place at the carbonyl group with retention of the nitrone group. Stable nitroxyl radicals --spiroimidazoisoxazole derivatives -are formed in the oxidation of fJhydroximinonitrones.