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Oxidative dehydrogenation of coordinated 1,9-bis(2-pyridyl)-2,5,8-triazanonane through formation of a cobalt dioxygen complex intermediate

✍ Scribed by Raleigh, Carl J.; Martell, Arthur E.


Book ID
126101380
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
876 KB
Volume
24
Category
Article
ISSN
0020-1669

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The synthesis and structural characterization of manganese, iron, and cobalt complexes of bis[di(2-pyridyl)methyl]amine (bdpma) were investigated. The bdpma ligand can give rise to mono-or dimeric complexes. Moreover, bdpma can undergo oxidative degradation leading to 1,3,3-tris(2-pyridyl)-3Himidazo