Oxidative Degradation of Aromatic Pollutants by Chemical Models of Ligninase Based on Porphyrin Complexes

Oxidation of alkenes by a chiral non-por

Oxidation of alkenes by a chiral non-porphyrinic oxidizing catalyst based on the bleomycin-Fe(II) complex

✍ Akira Suga; Toru Sugiyama; Masami Otsuka; Masaji Ohno; Yukio Sugiura; Kenji Maed 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 626 KB

## A bs t r act A synthetic model for the metal binding site of bleomyein with 4dimethylaminopyridine nucleus, namely PYML-8, shows dioxygen activation up to 125% of that of bleomycin. [~-Methylstyrene is oxidized with the Fe(III)-H202, Fe(III)-PhlO, or Fe(II)-O2 complex systems of PYML-8 to give