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Oxidative decarboxylation of exo- and endo-2-carboxybornane with lead tetra-acetate.

✍ Scribed by G.E. Gream; D. Wege

Book ID: 104223678
Publisher: Elsevier Science
Year: 1967
Tongue: French
Weight: 391 KB
Volume: 8
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)90538-0

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✦ Synopsis

The mechanism of the oxidative decarboxylation of aliphatic acids with lead tetra-aoetata has reoeived considerable attention in recent years (I-4). As a result of a study of the action of the above reagent and pyridine on exe-and endo-2norbornane carboxylic acids (I and II respeotively) in benzene and acetonitrile as solvents, Corey and Casanova (1) conclu-* The analyses were carried out by vapour phase chromatography using a 300' Ukon capillary column.

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