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Oxidative decarboxylation of alcohol hemiacetals of .alpha.-keto carboxylic acids with N-iodosuccinimide

โœ Scribed by Beebe, Thomas R.; Baldridge, Ruth; Beard, Mark; Cooke, Denette; DeFays, Isabelle; Hensley, Vivian; Hua, Dat; Lao, Jia Cheng; McMillen, Doug


Book ID
125974187
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
277 KB
Volume
52
Category
Article
ISSN
0022-3263

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Oxidative decarboxylation of ฮฑ-keto carb
โœ Wataru Ando; Hajime Miyazaki; Takeshi Akasaka ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 194 KB

Photosensitized oxygenation of a-keto carboxylic acids in the presence of diazo compounds afforded the corresponding carboxylic acids and carbon dioxide in high yields; oxidative decarboxylation by carbonyl oxides occurred. Hydroxylations catalyzed by several dioxygenases require cc-keto carboxylic