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Oxidative deamination of primary amines by copper halide nitrosyls. The formation of geminal dihalides

✍ Scribed by Doyle, Michael P.; Siegfried, Bernard; Hammond, James J.


Book ID
126804972
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
383 KB
Volume
98
Category
Article
ISSN
0002-7863

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We reported recently that both t-butyl thionitrite')and t-butyl thionitrate')can be prepared simply by treating t-butyl mercaptan with dinitrogen tetraoxide. We now have found that various arylamines reacted readily with either t-butyl thionitrite or t-butyl thionitrate and copper(I1) halides under