Oxidative Cyclization of Amino Alcohols Catalyzed by a Cp*Ir Complex. Synthesis of Indoles, 1,2,3,4-Tetrahydroquinolines, and 2,3,4,5-Tetrahydro-1-benzazepine.
β Scribed by Ken-ichi Fujita; Kazunari Yamamoto; Ryohei Yamaguchi
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A series of 4βaminoβtetrahydroβ2βbenzazepinβ3βone derivatives (AcβAbaβXxxβNHMe) were prepared as tetrapeptide mimetics. Considering the structural resemblance with the soβcalled Freidinger lactams, their propensity to adopt a Ξ²βturn conformation was investigated by NMR spectroscopy (sol