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Oxidative coupling of some 2,6-disubstituted phenols

✍ Scribed by J Malcolm Bruce; S.E Paulley


Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
245 KB
Volume
10
Category
Article
ISSN
0032-3861

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Oxidative Coupling Of 2-Alkyl-6,6-dimeth
✍ Shaochun You; Markus Neuenschwander πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 German βš– 789 KB

CuC1,-Induced oxidative coupling of 2-(rertbutyl)-6,6-dimethylpentafulvenyl anion 9 predominantly takes place at C(7) and C(5) to give [7-71 and (7-51 coupling products 15 and 16 in 35 and 47% yields, respectively (Scheme 3 ) whose structures are elucidated from IDand 2D-NMR analysis. Compared with