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Oxidative coupling of malononitrile with formation of 1,1,2,3,3-pentacyanopropene salts

✍ Scribed by Vladimir A. Kaminskii; Oleg Yu. Slabko; Andrey V. Kachanov; Boris V. Buhvetskii

Book ID: 104252620
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 92 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)02509-1

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✦ Synopsis

A simple and convenient route for the synthesis of 1,1,2,3,3-pentacyanopropene salts is reported. These salts are formed by interaction of malononitrile with SeO 2 in presence of organic N-containing bases or pyridinium salts.

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