Oxidative cleavage of silicon-carbon bond with trimethylamine-N-oxide. New access to primary alcohols and aldehydes from terminal alkenes and alkynes

✍ Scribed by Hideki Sakurai; Masatomo Ando; Nobuo Kawada; Kazuhiko Sato; Akira Hosomi

• Publisher: Elsevier Science
• Year: 1986
• Tongue: French
• Weight: 128 KB
• Volume: 27
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)83944-1

✦ Synopsis

Oxidative cZeavage of carbon-&Z&on bond of organosiZanes with trimethyZwnine-N-oxide is achieved under mild. conditions. The reaction occurs chemoseZectiveZy irrespective