Oxidative Cleavage and Rearrangement of Aryl Epoxides Using Iodosylbenzene: on Criegee 's Trail
β Scribed by Havare, Nizam; Plattner, Dietmar A.
- Book ID
- 118759237
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- German
- Weight
- 177 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The epoxidation of 2-styrylchromones 2a-h using Jacobsen's Mn(III)[salen] complex 1 as catalyst is reported for the first time. Several studies were performed using both hydrogen peroxide and iodosylbenzene as oxidants, in order to obtain the , -epoxy-2-styrylchromones 3a-h regioselectively. Due to
Aryl-substituted epoxides undergo smooth rearrangement in the presence of 0.01-0.1 mol% Bi(OTf) 3 β’xH 2 O. The rearrangement is regioselective with aryl-substituted epoxides, and products arise from cleavage of the benzylic C O bond. The highly catalytic nature of this method coupled with the fact t
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v